Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery

被引：67

作者：

Stoeck, Ulrich ^{[1
]}

Senkovska, Irena ^{[1
]}

Bon, Volodymyr ^{[1
]}

Krause, Simon ^{[1
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 06期

关键词：

NITRIC-OXIDE ADSORPTION; STORAGE; ETHYLENE; CONSTRUCTION; CAPACITY;

D O I：

10.1039/c4cc07920e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new mesoporous metal-organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal-organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm(3) g(-1) and a specific BET surface area of 4081 and 6344 m(2) g(-1), respectively, and high gas uptake at room temperature and high pressure.

引用

页码：1046 / 1049

页数：4

共 26 条

[11] A supermolecular building approach for the design and construction of metal-organic frameworks [J].

Guillerm, Vincent ;

Kim, Dongwook ;

Eubank, Jarrod F. ;

Luebke, Ryan ;

Liu, Xinfang ;

Adil, Karim ;

Lah, Myoung Soo ;

Eddaoudi, Mohamed .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :6141-6172

[12] Ethylene Removal and Fresh Product Storage: A Challenge at the Frontiers of Chemistry. Toward an Approach by Photocatalytic Oxidation [J].

Keller, Nicolas ;

Ducamp, Marie-Noelle ;

Robert, Didier ;

Keller, Valerie .

CHEMICAL REVIEWS, 2013, 113 (07) :5029-5070

[13] Biomedical Applications of Metal Organic Frameworks [J].

Keskin, Seda ;

Kizilel, Seda .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (04) :1799-1812

[14]

Li JR, 2010, NAT CHEM, V2, P893, DOI [10.1038/nchem.803, 10.1038/NCHEM.803]

[15] Highly porous metal-organic framework sustained with 12-connected nanoscopic octahedra [J].

Lu, Weigang ;

Yuan, Daqiang ;

Makal, Trevor A. ;

Wei, Zhangwen ;

Li, Jian-Rong ;

Zhou, Hong-Cai .

DALTON TRANSACTIONS, 2013, 42 (05) :1708-1714

[16] Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal-Organic Frameworks [J].

McKinlay, A. C. ;

Eubank, J. F. ;

Wuttke, S. ;

Xiao, B. ;

Wheadey, P. S. ;

Bazin, P. ;

Lavalley, J. -C. ;

Daturi, M. ;

Vimont, A. ;

De Weireld, G. ;

Horcajada, P. ;

Serre, C. ;

Morris, R. E. .

CHEMISTRY OF MATERIALS, 2013, 25 (09) :1592-1599

[17] Review - Recent developments in nitric oxide donor drugs [J].

Miller, M. R. ;

Megson, I. L. .

BRITISH JOURNAL OF PHARMACOLOGY, 2007, 151 (03) :305-321

[18] A rare example of a porous Ca-MOF for the controlled release of biologically active NO [J].

Miller, Stuart R. ;

Alvarez, Elsa ;

Fradcourt, Lucie ;

Devic, Thomas ;

Wuttke, Stefan ;

Wheatley, Paul S. ;

Steunou, Nathalie ;

Bonhomme, Christian ;

Gervais, Christel ;

Laurencin, Danielle ;

Morris, Russell E. ;

Vimont, Alexandre ;

Daturi, Marco ;

Horcajada, Patricia ;

Serre, Christian .

CHEMICAL COMMUNICATIONS, 2013, 49 (71) :7773-7775

[19] The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets [J].

O'Keeffe, Michael ;

Peskov, Maxim A. ;

Ramsden, Stuart J. ;

Yaghi, Omar M. .

ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (12) :1782-1789

[20] Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks [J].

Perry, John J., IV ;

Perman, Jason A. ;

Zaworotko, Michael J. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1400-1417

← 1 2 3 →