Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery

被引：67

作者：

Stoeck, Ulrich ^{[1
]}

Senkovska, Irena ^{[1
]}

Bon, Volodymyr ^{[1
]}

Krause, Simon ^{[1
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 06期

关键词：

NITRIC-OXIDE ADSORPTION; STORAGE; ETHYLENE; CONSTRUCTION; CAPACITY;

D O I：

10.1039/c4cc07920e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new mesoporous metal-organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal-organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm(3) g(-1) and a specific BET surface area of 4081 and 6344 m(2) g(-1), respectively, and high gas uptake at room temperature and high pressure.

引用

页码：1046 / 1049

页数：4

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