A novel route for large-scale synthesis of [Au(NHC)(OH)] complexes

被引:34
作者
Nahra, Fady [1 ]
Patrick, Scott R. [1 ]
Collado, Alba [1 ]
Nolan, Steven P. [1 ,2 ]
机构
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] King Saud Univ, Dept Chem, Coll Sci, Riyadh 11451, Saudi Arabia
基金
英国工程与自然科学研究理事会;
关键词
Gold; ynthesis; NHC; Large scale; Coordination chemistry; N-HETEROCYCLIC CARBENE; GOLD CATALYSIS; NHC; REACTIVITY; HYDROXIDES; PHOSPHINE;
D O I
10.1016/j.poly.2014.06.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel route for the large-scale synthesis of [Au(NHC)(OH)] complexes is reported. Using this new methodology, several [Au(NHC)(OH)] complexes were readily and efficiently accessed on multi-gram scale (up to 20 g). (C) 2014 The Authors. Published by Elsevier Ltd.
引用
收藏
页码:59 / 62
页数:4
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