Recent Advances and Perspectives in Transition Metal-Catalyzed 1,4-Functionalizations of Unactivated 1,3-Enynes for the Synthesis of Allenes

被引：176

作者：

Fu, Liang ^{[1
,2
]}

Gressies, Steffen ^{[1
,2
]}

Chen, Pinhong ^{[1
,2
]}

Liu, Guosheng ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, Shanghai Hongkong Joint Lab Chem Synth, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2020年 / 38卷 / 01期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; LIGAND PROPERTIES; FACILE SYNTHESIS; REARRANGEMENTS; ALDEHYDES; ACCESS; ESTERS; TRANSMETALATION;

D O I：

10.1002/cjoc.201900277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Classic methods for the synthesis of allenes usually introduce only one functional group into products. In this review, we highlight the recent advances and perspectives in the synthesis of allenes by transition metal-catalyzed 1,4-functionalization of unactivated 1,3-enynes.

引用

页码：91 / 100

页数：10

共 85 条

[51] Copper-Catalyzed N-Allenylation of Allylic Sulfonamides [J].

Persson, Andreas K. A. ;

Johnston, Eric V. ;

Backvall, Jan-E. .

ORGANIC LETTERS, 2009, 11 (17) :3814-3817

[52] Organocatalytic Formation of Chiral Trisubstituted Allenes and Chiral Furan Derivatives [J].

Poulsen, Pernille H. ;

Li, Yang ;

Lauridsen, Vibeke H. ;

Jorgensen, Danny K. B. ;

Palazzo, Teresa A. ;

Meazza, Marta ;

Jorgensen, Karl Anker .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (33) :10661-10665

[53] Direct and stereospecific synthesis of allenes via reduction of propargylic alcohols with CP2Zr(H)Cl [J].

Pu, Xiaotao ;

Ready, Joseph M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10874-+

[54] Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes [J].

Qian, Hui ;

Yu, Xiuzhao ;

Zhang, Junliang ;

Sun, Jianwei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (48) :18020-18023

[55] A NOVEL SYNTHESIS OF SUBSTITUTED ALLENES [J].

RONA, P ;

CRABBE, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (12) :3289-&

[56] Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates [J].

Sang, Hui Leng ;

Yu, Songjie ;

Ge, Shaozhong .

ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (08) :1284-1287

[57]

Schuster H.F., 1984, ALLENES ORGANIC SYNT

[58] CHEMISTRY OF GEM-DIHALOCYCLOPROPANES .6. A NOVEL SYNTHESIS OF CYCLOPENTADIENES AND FULVENES [J].

SKATTEBOL, L .

TETRAHEDRON, 1967, 23 (03) :1107-+

[59] Cationic Rhodium(I)-dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade [J].

Tanaka, Ken ;

Okazaki, Eri ;

Shibata, Yu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10822-+

[60] New Metal-Free One-Pot Synthesis of Substituted Allenes from Enones [J].

Tang, Meng ;

Fan, Chun-An ;

Zhang, Fu-Min ;

Tu, Yong-Qiang ;

Zhang, Wen-Xue ;

Wang, Ai-Xia .

ORGANIC LETTERS, 2008, 10 (24) :5585-5588

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