Synthesis, characterization and lithium-storage performance of MoO2/carbon hybrid nanowires

被引:142
作者
Cao, Qingsheng
Yang, Lichun
Lu, Xinchun
Mao, Jianjiang
Zhang, Yahong
Wu, Yuping
Tang, YI
机构
[1] Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University
[2] Center of Analysis Measurement, Fudan University
关键词
FIELD-EMISSION PROPERTIES; MOLYBDENUM DIOXIDE; OXIDE NANOWIRES; MOO3; NANOBELTS; ANODE MATERIAL; ION BATTERIES; NANORODS; NANOTUBES; CHEMISTRY; ARRAYS;
D O I
10.1039/b921001f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper presents a novel strategy to synthesize MoO2/carbon nanowires based on organic-inorganic hybrid nanocomposites with nanometre periodic structures. The organic-inorganic hybrid precursors provide uniform reactions throughout the composites for achieving novel carbon-hybrid structures and nano-morphology via easy calcination. Through the systematic physical characterization including scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, etc., the one-dimensional and carbon-hybrid structure of MoO2/C nanowires was confirmed. This synthetic strategy is also proved universal for other novel MoO2/C nanostructures based on various organic-inorganic hybrid precursors. Furthermore, the MoO2/C hybrid nanowires show good rate capability even at the high current density of 1000 mA g(-1) as anode material for lithium ion battery.
引用
收藏
页码:2807 / 2812
页数:6
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