The Heck olefination reaction; A DFT study of the elimination pathway

被引：58

作者：

Deeth, RJ ^{[1
]}

Smith, A

Hii, KK

Brown, JM

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(98)00398-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Theoretical studies of the pathway in the Heck reaction between ethene and a methyl electrophile at [Pd(H(2)ACH(2)AH(2))(CH3)(H2C=CH2)](+) (A = P, N) reveal intermediates with an agostic H which is the one preferentially transferred to base. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3229 / 3232

页数：4

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