Reactions of a dibismuthane and of cyclobismuthanes with metal carbonyls -: Syntheses of complexes with R2Bi-, RBi-, Bi2- and Bin-ligands (R = Me3CCH2, Me3SiCH2)

被引：16

作者：

Balázs, L ^{[1
]}

Breunig, HJ ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, FB02, D-28334 Bremen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 12期

关键词：

bismuth; iron; manganese;

D O I：

10.1002/zaac.200400213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [FC2(CO)(9)] with [(Me3CCH2)(4)Bi](2) or cyclo(Me3SiCH2Bi)(n) (n = 3 - 5) lead to the complexes [(R2Bi)(2)Fe(CO)(4)], [RBiFe(CO)(4)](2) [R = MeXCH2, Me3SiCH2] and [Bi2Fe3(CO)(9)]. [Bi-2{Mn(CO)(2)C5H4CH3}(3)] forms in a photochemical reaction of [Mn(CO)(3)C5H4CH3] with cyclo-(Me(3)SiCH(2B)i)(n).

引用

页码：1937 / 1940

页数：4

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