Four cobalt(III) Schiff base complexes - Structural, spectroscopic and electrochemical studies

被引：38

作者：

Pogany, Lukas ^{[1
]}

Moncol, Jan ^{[1
]}

Gal, Miroslav ^{[1
]}

Salitros, Ivan ^{[1
]}

Boca, Roman ^{[1
,2
]}

机构：

[1] Slovak Univ Technol Bratislava, Inst Inorgan Chem, SK-81237 Bratislava, Slovakia

[2] Univ SS Cyril & Methodius, Dept Chem FPV, Trnava 91701, Slovakia

来源：

INORGANICA CHIMICA ACTA | 2017年 / 462卷

关键词：

Schiff base; Cobalt(III) complexes; Crystal structure; Spectral properties; Cyclic voltammetry; SPIN-CROSSOVER; MANNICH-BASES; CRYSTAL-STRUCTURES; ELECTRON-TRANSFER; METAL-COMPLEXES; LIGANDS; ANTIBACTERIAL; 5-COORDINATE; ANTIFUNGAL; PROTOTYPES;

D O I：

10.1016/j.ica.2017.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new complexes of the general formula [Co(L-n)Cl] (where L-n is dianion of pentadentate Schiff base ligand N, N'-bis(2-hydroxybenzylidene)-1,6-diamino-3-azahexane = H2L1, N, N'-bis(2-hydroxy-3methoxy- benzylidene)-1,6-diamino-3-azahexane = H2L2, N, N'-bis(3-ethoxy-2-hydroxy-benzylidene)1,6- diamino-3-azahexane = H2L3 or N, N'-bis(2-hydroxybenzylidene)-1,7-diamino-4-methyl-4-azaheptane = H2L4) have been synthesized and characterized by elemental analyses, IR, UV-VIS. The redox properties have been studied by cyclic voltammetry. Moreover, the crystal structures of 1, 2 and 3 have been determined by X-ray diffraction and H-1 NMR spectrum of 4 has been obtained. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：23 / 29

页数：7

共 40 条

[1] Synthesis and spectroscopic studies on ternary bis-Schiff-base complexes having oxygen and/or nitrogen donors [J].

Abu-Hussen, AAA .

JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (02) :157-176

[2] Investigation of cobalt(III)-triazole systems as prototypes for hypoxia-activated drug delivery [J].

Aguiar de Souza, Isabela Cristina ;

Faro, Leticia Villafranca ;

Pinheiro, Carlos Basilio ;

Gomes Gonzaga, Daniel Tadeu ;

da Silva, Fernando de Carvalho ;

Ferreira, Vitor Francisco ;

Miranda, Fabio da Silva ;

Scarpellini, Marciela ;

Lanznaster, Mauricio .

DALTON TRANSACTIONS, 2016, 45 (35) :13671-13674

[3] Spectroscopic and magnetic properties and structure of a five-coordinate, O2-binding cobalt(II) Schiff base complex and of the copper(II) analogue [J].

Boca, R ;

Elias, H ;

Haase, W ;

Huber, M ;

Klement, R ;

Muller, L ;

Paulus, H ;

Svoboda, I ;

Valko, M .

INORGANICA CHIMICA ACTA, 1998, 278 (02) :127-135

[4] Periodic trends within a series of five-coordinate thiolate-ligated [MII(SMe2N4(tren))]+ (M = Mn, Fe, Co, Ni, Cu, Zn) complexes, including a rare example of a stable CuII-thiolate [J].

Brines, Lisa M. ;

Shearer, Jason ;

Fender, Jessica K. ;

Schweitzer, Dirk ;

Shoner, Steven C. ;

Barnhart, David ;

Kaminsky, Werner ;

Lovell, Scott ;

Kovacs, Julie A. .

INORGANIC CHEMISTRY, 2007, 46 (22) :9267-9277

[5] Coordination Modes of a Schiff Base Pentadentate Derivative of 4-Aminoantipyrine with Cobalt(II), Nickel(II) and Copper(II) Metal Ions: Synthesis, Spectroscopic and Antimicrobial Studies [J].

Chandra, Sulekh ;

Jain, Deepali ;

Sharma, Amit Kumar ;

Sharma, Pratibha .

MOLECULES, 2009, 14 (01) :174-190

[6] Metal complexes of chiral binaphthyl Schiff-base ligands and their application in stereoselective organic transformations [J].

Che, CM ;

Huang, JS .

COORDINATION CHEMISTRY REVIEWS, 2003, 242 (1-2) :97-113

[7] Metal-Salen Schiff base complexes in catalysis: practical aspects [J].

Cozzi, PG .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (07) :410-421

[8] Schiff bases: A short review of their antimicrobial activities [J].

da Silva, Cleiton M. ;

da Silva, Daniel L. ;

Modolo, Luzia V. ;

Alves, Rosemeire B. ;

de Resende, Maria A. ;

Martins, Cleide V. B. ;

de Fatima, Angelo .

JOURNAL OF ADVANCED RESEARCH, 2011, 2 (01) :1-8

[9] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[10] Thermal spin crossover in Mn(II), Mn(III), Cr(II) and Co(III) coordination compounds [J].

Garcia, Y ;

Gütlich, P .

SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS II, 2004, 234 :49-62

← 1 2 3 4 →