Structural, electric and dielectric properties of perovskite based nanoparticles for energy applications

被引:18
作者
Nazir, Arif [1 ]
Khalid, Fraz [1 ]
Rehman, Shafiq ur [1 ]
Sarwar, Masood [2 ]
Iqbal, Munawar [1 ]
Yaseen, Muhammad [3 ]
Khan, Muhammad Iftikhar [4 ]
Abbas, Mazhar [5 ]
机构
[1] Univ Lahore, Dept Chem, Lahore, Pakistan
[2] Govt Islamia Degree Coll Sambrial, Sialkot, Pakistan
[3] Univ Agr Faisalabad, Dept Phys, Faisalabad, Pakistan
[4] Univ Lahore, Dept Phys, Lahore, Pakistan
[5] UVAS, Coll Vet & Anim Sci, Dept Basic Sci, Jhang Campus, Lahore, Pakistan
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2021年 / 235卷 / 06期
关键词
catalytic performance; cathode; co-precipitation; electronic properties; nanocomposites; perovskites; MICROWAVE COMBUSTION SYNTHESIS; KUTAHYA MINING AREA; COPRECIPITATION SYNTHESIS; OXIDE; PERFORMANCE; ANODE; GEL; CO; NANOSTRUCTURES; ANTIBACTERIAL;
D O I
10.1515/zpch-2019-1558
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A nanocomposite electrode, obtained by combining two high performance perovskite materials, such as lanthanum strontium cobalt ferrite, La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) and gadolinium doped ceria, Ce0.85Gd0.15O1.5 (GDC), were investigated as a promising cathode for moderate temperature solid oxide fuel cells (SOFCs). The synthesized material has good conductivity and catalytic performance. The purpose of this synthesis was to prepare a stable and highly performing nanocomposite cathode material. In this research work, LSCF and GDC were separately synthesized by co-precipitation and solid-state reaction method to gain a homogeneous perovskite phase. Varying concentrations of LSCF-GDC composite with GDC (10 wt.%, 20 wt.% and 30 wt.%) were synthesized followed by calcination at 600 degrees C to remove water content and to achieve an adequate porous structure for oxygen absorption and desorption. These fabricated LSCF, GDC, and the nanocomposite specimens were characterized for microstructure, particle size etc. via. X-ray diffraction method (XRD), scanning electron microscope (SEM) and the laser particle size analyzer. This procedural approach helps to expand new methods for generating bi-functional duel nano-sized perovskites with great performance and stability which can be utilized for advancement of renewable energy sectors especially for rechargeable fuel batteries.
引用
收藏
页码:769 / 784
页数:16
相关论文
共 58 条
[1]   Kinetics and Equilibrium Studies of Eriobotrya Japonica: A Novel Adsorbent Preparation for Dyes Sequestration [J].
Ahmad, Mukhtar ;
Abbas, Ghulam ;
Haider, Rizwan ;
Jalal, Fatima ;
Shar, Ghulam Abbas ;
Soomro, Gul Afshan ;
Qureshi, Naseem ;
Iqbal, Munawar ;
Nazir, Arif .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2019, 233 (10) :1469-1484
[2]  
Alasadi AM, 2019, CHEM INT, V5, P258, DOI 10.5281/zenodo.2644985
[3]  
[Anonymous], 2017, CHEM INT, DOI DOI 10.5281/zenodo.1473351
[4]   Zn-doped SiO2 nanoparticles preparation and characterization under the effect of various solvents: Antibacterial, antifungal and photocatlytic performance evaluation [J].
Arshad, Muhammad ;
Qayyum, Abdul ;
Shar, Ghulam Abbas ;
Soomro, Gul Afshan ;
Nazir, Arif ;
Munir, Bushra ;
Iqbal, Munawar .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2018, 185 :176-183
[5]   Hydrothermal synthesis of CoyZnyMn1-2yFe2O4 nanoferrites: Magneto optical investigation [J].
Asiri, S. ;
Sertkol, M. ;
Guner, S. ;
Gungunes, H. ;
Batoo, K. M. ;
Saleh, T. A. ;
Sozeri, H. ;
Almessiere, M. A. ;
Manikandan, A. ;
Baykal, A. .
CERAMICS INTERNATIONAL, 2018, 44 (05) :5751-5759
[6]  
Awwad A M., 2020, Chemistry International, V6, P42, DOI [DOI 10.5281/ZENODO.3243157, 10.5281/ZENODO.3243157]
[7]   Structural, Dielectric and Magnetic Studies of Perovskite [Gd1-xMxCrO3 (M = La, Co, Bi)] Nanoparticles: Photocatalytic Degradation of Dyes [J].
Bibi, Ismat ;
Hussain, Sabir ;
Majid, Farzana ;
Kamal, Shagufta ;
Ata, Sadia ;
Sultan, Misbah ;
Din, Muhammad Imran ;
Iqbal, Munawar ;
Nazir, Arif .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2019, 233 (10) :1431-1445
[8]   Nickel nanoparticle synthesis using Camellia Sinensis as reducing and capping agent: Growth mechanism and photo-catalytic activity evaluation [J].
Bibi, Ismat ;
Kamal, Shagufta ;
Ahmed, Adeel ;
Iqbal, Munawar ;
Nouren, Shazia ;
Jilani, Kashif ;
Nazar, Nosheen ;
Amir, Muhammad ;
Abbas, Ansar ;
Ata, Sadia ;
Majid, Farzana .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2017, 103 :783-790
[9]   Morphology, performance and stability of multi-bore capillary La0.6Sr0.4Co0.2Fe0.8O3-δ oxygen transport membranes [J].
Chi, Yunsi ;
Li, Tao ;
Wang, Bo ;
Wu, Zhentao ;
Li, Kang .
JOURNAL OF MEMBRANE SCIENCE, 2017, 529 :224-233
[10]   Integration of Spin-Coated Nanoparticulate-Based La0.6Sr0.4CoO3-δ Cathodes into Micro-Solid Oxide Fuel Cell Membranes [J].
Evans, A. ;
Benel, C. ;
Darbandi, A. J. ;
Hahn, H. ;
Martynczuk, J. ;
Gauckler, L. J. ;
Prestat, M. .
FUEL CELLS, 2013, 13 (03) :441-444