A crystal engineering study copper(II) complexes with 2,4-diamino-6-(4-pyridyl)-1,3,5-triazine (3) and 2-amino-4-phenylamino-6-(4-pyridyl)-1,3,5-triazine (4)

被引:38
作者
Chan, CW [1 ]
Mingos, DMP [1 ]
White, AJP [1 ]
Williams, DJ [1 ]
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,INORGAN & CHEM CRYSTALLOG RES LABS,LONDON SW7 2AY,ENGLAND
基金
英国生物技术与生命科学研究理事会;
关键词
D O I
10.1016/0277-5387(95)00442-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structures of two newly synthesized ligands based on 2,4,6-triamino-1,3,5-triazine (3 and 4) have been determined and their hydrogen-bonded and pi-pi stacked supramolecular structures have been analysed. Two copper(II) complexes of these ligands (5 and 6) illustrate the formation of metal-ion directed self-assembled superstructures whose networks are markedly modified as a consequence of the introduction of the coordinated metal centres.
引用
收藏
页码:1753 / 1767
页数:15
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