A crystal engineering study copper(II) complexes with 2,4-diamino-6-(4-pyridyl)-1,3,5-triazine (3) and 2-amino-4-phenylamino-6-(4-pyridyl)-1,3,5-triazine (4)

被引：38

作者：

Chan, CW ^{[1
]}

Mingos, DMP ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,INORGAN & CHEM CRYSTALLOG RES LABS,LONDON SW7 2AY,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 11期

基金：

英国生物技术与生命科学研究理事会;

关键词：

D O I：

10.1016/0277-5387(95)00442-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of two newly synthesized ligands based on 2,4,6-triamino-1,3,5-triazine (3 and 4) have been determined and their hydrogen-bonded and pi-pi stacked supramolecular structures have been analysed. Two copper(II) complexes of these ligands (5 and 6) illustrate the formation of metal-ion directed self-assembled superstructures whose networks are markedly modified as a consequence of the introduction of the coordinated metal centres.

引用

页码：1753 / 1767

页数：15

共 18 条

[1]

BURROWS AD, 1995, IN PRESS CHEM SOC RE

[2] STRUCTURAL INVESTIGATIONS OF METAL-NITRATE COMPLEXES .5. CRYSTAL AND MOLECULAR STRUCTURES OF "DINITRATOTRIS(PYRIDINE)-COBALT(II), DINITRATORIS(PYRIDINE)-COPPER(II), AND DINITRATORIS(PYRIDINE)-ZINC(II) [J].