The first oligopeptide derivative of 1′-aminoferrocene-1-carboxylic acid shows helical chirality with antiparallel strands

被引:105
作者
Barisic, L
Dropucic, M
Rapic, V
Pritzkow, H
Kirin, SI
Metzler-Nolte, N
机构
[1] Univ Zagreb, Fac Food Technol & Biotechnol, HR-10000 Zagreb, Croatia
[2] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
[3] Heidelberg Univ, Inst Pharm & Mol Biotechnol, D-69120 Heidelberg, Germany
关键词
D O I
10.1039/b407771g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The unnatural organometallic amino acid 1'-aminoferrocene-1-carboxylic acid (Fca) induces a turn structure in a tetrapeptide with anti-parallel strands which is stabilized by two intramolecular hydrogen bonds in the solid state and in solution.
引用
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页码:2004 / 2005
页数:2
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