Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling reactions

被引：332

作者：

Xue, Liqin ^{[1
]}

Lin, Zhenyang ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 05期

关键词：

DENSITY-FUNCTIONAL THEORY; N-HETEROCYCLIC CARBENE; OXIDATIVE ADDITION; SUZUKI-MIYAURA; REDUCTIVE ELIMINATION; STILLE REACTION; ARYL CHLORIDES; HECK REACTION; C-H; TRANSMETALATION STEP;

D O I：

10.1039/b814973a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalysed processes for the formation of carbon-carbon bonds, i.e., coupling reactions of organic halides ((RX)-X-1) and main-group organometallic compounds ((RM)-M-2) are most frequently applied in synthesizing biologically and pharmaceutically important organic molecules. In this article, we provide a critical review on theoretical studies of the palladium-catalysed carbon-carbon cross-coupling reactions, and give an up-to-date summary of the current understanding of the cross-coupling reactions from a theoretical point of view (108 references).

引用

页码：1692 / 1705

页数：14

共 114 条

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