Assembly of a manganese(II) pyridine-3,4-dicarboxylate polymeric network based on infinite Mn-O-C chains

被引：77
作者：
Chen, W
Yue, Q
Chen, C
Yuan, HM
Xu, W
Chen, JS [1 ]
Wang, SN
机构：
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130023, Peoples R China
[2] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
来源：
DALTON TRANSACTIONS | 2003年 / 01期
关键词：
D O I：
10.1039/b210462h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A unique metal-organic polymer MncirclePDB.H2O (H2PDB = pyridine-3,4-dicarboxylic acid), with weak antiferromagnetic interactions both between the manganese(II) centers of an infinite Mn-O-C chain and between the adjacent chains, has been synthesized by the hydrothermal reaction of Mn(CH3COO)(2).4H(2)O with H2PDB; X-ray diffraction shows that the polymer possesses a one-dimensional rectangular channel built up from pyridine rings and pseudo-layers formed by infinite straight Mn-O-C chain building units.
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页码：28 / 30
页数：3
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