Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

被引：17
作者：
Han, Song-De [1 ]
Zhang, Xiu-Rong [1 ]
Pan, Jie [1 ]
Mu, Ying [1 ]
Li, Jin-Hua [1 ]
Wang, Guo-Ming [1 ]
机构：
[1] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 35期
关键词：
METAL-ORGANIC FRAMEWORKS; LARGE 24-RING CHANNELS; COORDINATION POLYMERS; IONOTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; HELICAL CHAINS; PHOSPHATE; ADSORPTION; TRANSFORMATION; MANGANESE(II);
D O I：
10.1039/c8dt02761g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn-2(HPO3)(2)(BIP)]H2O (1) and [Zn-3(HPO3)(3)(BIP)(H2O)]H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(ii) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(ii) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied.
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收藏
页码：12468 / 12473
页数：6
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