Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

被引：17

作者：

Han, Song-De ^{[1
]}

Zhang, Xiu-Rong ^{[1
]}

Pan, Jie ^{[1
]}

Mu, Ying ^{[1
]}

Li, Jin-Hua ^{[1
]}

Wang, Guo-Ming ^{[1
]}

机构：

[1] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Shandong, Peoples R China

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 35期

关键词：

METAL-ORGANIC FRAMEWORKS; LARGE 24-RING CHANNELS; COORDINATION POLYMERS; IONOTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; HELICAL CHAINS; PHOSPHATE; ADSORPTION; TRANSFORMATION; MANGANESE(II);

D O I：

10.1039/c8dt02761g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn-2(HPO3)(2)(BIP)]H2O (1) and [Zn-3(HPO3)(3)(BIP)(H2O)]H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(ii) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(ii) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied.

引用

页码：12468 / 12473

页数：6

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