Synthesis and structure of products of interaction of H[AuCl4] with H2DMG and pyridine

被引：14

作者：

Bourosh, Paulina ^{[1
]}

Bologa, Olga

Simonov, Yurii

Gerbeleu, Nicolae

Lipkowski, Janusz

Gdaniec, Maria

机构：

[1] Moldavian Acad Sci, Inst Appl Sci, Kishinev 2028, Moldova

[2] Moldavian Acad Sci, Inst Chem, Kishinev 2028, Moldova

[3] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

[4] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 10期

关键词：

Au(III); crystal structure; Au center dot center dot center dot Cl and Au center dot center dot center dot Au interactions; COMPLEXES; GOLD(I); BINUCLEAR; MONONUCLEAR; CRYSTAL; CHAIN;

D O I：

10.1016/j.ica.2007.03.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two complexes of gold of the compositions [Au(DMG)ClPy] (1) and [AuCl2Py2][AuCl4] center dot 2[AuCl3Py] (2), where H(2)DMG was dimethylglyoxime, were synthesized as the products of interaction of H[AuCl4] center dot 4H(2)O with H(2)DMG in the presence of pyridine and characterized by X-ray structural analysis. It was shown that depending on the synthetic conditions, the final product represents a molecular complex 1 or an ionic complex 2, in the latter one the charged and neutral species being combined via Au center dot center dot center dot Cl or Au center dot center dot center dot Au interactions. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：3250 / 3254

页数：5

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