Preparation of Y2O3-ZrO2-CeO2 solid solution by co-precipitation and its electrical property

被引:18
|
作者
Dong, Yihang [1 ]
Liu, Zhaoyang [2 ]
Pang, Lipeng [3 ]
Han, Ye [1 ]
Yao, Shuyu [1 ]
Wang, Xiangnan [1 ]
机构
[1] Shandong Univ Sci & Technol, Sch Mat Sci & Engn, Qingdao 266590, Peoples R China
[2] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
[3] Shougang Jingtang Iron&steel Co Ltd, Tangshan 063200, Peoples R China
关键词
Co-precipitation; XRD; TG-DSC; Mixed conductor; Electrical conductivity; MICROSTRUCTURE; CATHODE; CONDUCTIVITY; ZIRCONIA; ELECTROLYTE;
D O I
10.1016/j.physb.2021.412972
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
\{(Y2O3)0.08(ZrO2)0.92}1-x (CeO2)x (0 < x < 0.6) is synthesized by co-precipitation method. Thermal analysis, phase structure, lattice constant, micro-morphology, elements distribution, density, open porosity and electrical conductivity are measured by TG, DSC, XRD, GSAS, SEM, EDS, Archimedes method and EIS respectively, and the influence of CeO2 content on the above properties are investigated. TG-DSC results show that the weight loss of the sample is mainly due to the decomposition of the initial powder, forming a solid solution above -600 degrees C. XRD results show that {(Y2O3)0.08(ZrO2)0.92}1-x (CeO2)x (0 < x < 0.6) is a cubic solid solution, and the lattice parameters and volume increase with the increase of CeO2 content. SEM results show that YZC is a dense sintered body. Density and open porosity of YZC sample are -4.5 g cm-3 and -0.12, respectively. The electrical conductivity results show that the conductivity of {(Y2O3)0.08(ZrO2)0.92}1-x (CeO2)x (0 < x < 0.2) is equivalent, and then the conductivity decreases due to defect association with the increase of CeO2 content.
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页数:8
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