Studies on Preparation and Hydrogen Storage Properties of Dual-Metal Ferrocenyl Coordination Polymer Microspheres

被引：9
作者：
Sun, Ruoli [1 ]
Wang, Li [1 ]
Yu, Haojie [1 ]
Zain-ul-Abdin [1 ]
Chen, Yongsheng [1 ]
Khalid, Hamad [1 ]
Abbasi, Nasir M. [1 ]
Akram, Muhammad [1 ]
Vatsadze, Sergey Z. [2 ]
Lemenovskii, Dmitri A. [2 ]
机构：
[1] Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1-3, Moscow 119992, Russia
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2016年 / 26卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Hydrogen storage; Microspheres; Ferrocenyl coordination polymers; PYRIDYL-BIS-AMIDE; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; MIXED-LIGANDS; ACID; FE; DICARBOXYLATE; COMPLEXES; SYSTEMS; SERIES;
D O I：
10.1007/s10904-016-0361-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of dual-metal ferrocenyl coordination polymer microspheres (M1M2-CPMs, M1M2 = CoMn, CoCu, MnCu) were synthesized by the reaction of 1,1'-ferrocene dicarboxylic acid with mixed metal salts via solvothermal method. From SEM and TEM images, it was found that all the as-synthesized coordination polymers showed microspheres structures. The products were also characterized by X-ray photoelectron spectroscopy (XPS), fourier transform infrared (FT-IR), powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The M1M2-CPMs showed good thermostability and remained stable up to 250 A degrees C. These M1M2-CPMs exhibited hydrogen uptake capacity. More interestingly, through the comparison among three microspheres we found that the M1M2-CPMs with hollow structures showed better hydrogen uptake.
引用
收藏
页码：545 / 554
页数：10
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