Preparation of hexagonal nanoporous nickel hydroxide film and its application for electrochemical capacitor

被引：259

作者：

Zhao, Dan-Dan ^{[1
]}

Bao, Shu-Juan ^{[1
]}

Zhou, Wen-Ha ^{[1
]}

Li, Hu-Lin ^{[1
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 05期

基金：

中国国家自然科学基金;

关键词：

nanoporous nickel hydroxide film; hexagonal lyotropic liquid crystal template; electrodeposition; electrochemical capacitors (ECs); LIQUID-CRYSTALLINE PHASES; OXIDE; MANGANESE; ELECTRODE; SUPERCAPACITOR; DEPOSITION; STORAGE; SURFACE;

D O I：

10.1016/j.elecom.2006.11.030

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Nanoporous nickel hydroxide film has been successfully electrodeposited on titanium substrate from nickel nitrate dissolved in the aqueous domains of the hexagonal lyotropic liquid crystalline phase of Brij 56. Low-angle X-ray diffraction (XRD), transmission electron microscopy (TEM), and atomic force microscopy (AFM) studies show that the film has a regular nanostructure consisting of a hexagonal array of cylindrical pores with a repeat center-to-center spacing of about 7 nm. Preliminary electrochemical studies are carried out using cyclic voltammetry (CV) and chronopotentiometry technology. A maximum specific capacitance of 578 F g(-1) could be achieved for the nanoporous Ni(OH)(2) film electrode, suggesting its potential application in electrochemical capacitors. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：869 / 874

页数：6

共 26 条

[1] Mesoporous platinum films from lyotropic liquid crystalline phases
Attard, GS
Bartlett, PN
Coleman, NRB
Elliott, JM
Owen, JR
Wang, JH
[J]. SCIENCE, 1997, 278 (5339) : 838 - 840
[2] The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases
Bartlett, PN
Gollas, B
Guerin, S
Marwan, J
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (15) : 3835 - 3842
[3] Preparation of mesoporous nanocrystalline Co3O4 and its applicability of porosity to the formation of electrochemical capacitance
Cao, L
Lu, M
Li, HL
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (05) : A871 - A875
[4] Preparation of the novel nanocomposite Co(OH)2/ultra-stable Y zeolite and its application as a supercapacitor with high energy density
Cao, L
Xu, F
Liang, YY
Li, HL
[J]. ADVANCED MATERIALS, 2004, 16 (20) : 1853 - +
[5] Preparation of novel nano-composite Ni(OH)2/USY material and its application for electrochemical capacitance storage
Cao, L
Kong, LB
Liang, YY
Li, HL
[J]. CHEMICAL COMMUNICATIONS, 2004, (14) : 1646 - 1647
[6] Conway B.E., 1999, ELECTROCHEMICAL SUPE
[7] Preparation of high surface area nickel electrodeposit using a liquid crystal template technique
Ganesh, V
Lakshminarayanan, V
[J]. ELECTROCHIMICA ACTA, 2004, 49 (21) : 3561 - 3572
[8] Electrochemical supercapacitor material based on manganese oxide: preparation and characterization
Jiang, JH
Kucernak, A
[J]. ELECTROCHIMICA ACTA, 2002, 47 (15) : 2381 - 2386
[9] KARNATH PV, 1994, J ELECTROCHEM SOC, V141, P2956
[10] Characterization of sol-gel-derived cobalt oxide xerogels as electrochemical capacitors
Lin, C
Ritter, JA
Popov, BN
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) : 4097 - 4103

← 1 2 3 →