Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic Conditions

被引：82

作者：

Gustafson, J. ^{[1
]}

Westerstrom, R. ^{[1
]}

Balmes, O. ^{[2
]}

Resta, A. ^{[2
]}

van Rijn, R. ^{[2
,3
]}

Torrelles, X. ^{[4
]}

Herbschleb, C. T. ^{[3
]}

Frenken, J. W. M. ^{[3
]}

Lundgren, E. ^{[1
]}

机构：

[1] Lund Univ, Div Synchrotron Radiat Res, SE-22100 Lund, Sweden

[2] ESRF, F-38043 Grenoble, France

[3] Leiden Univ, Kamerlingh Onnes Lab, NL-2300 RA Leiden, Netherlands

[4] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 10期

基金：

瑞典研究理事会;

关键词：

PT-GROUP METALS; IN-SITU; ULTRAHIGH-VACUUM; NANOPARTICLES; REACTIVITY; RUTHENIUM;

D O I：

10.1021/jp910988b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a combination of surface X-ray diffraction and mass spectrometry at realistic pressures, the CO oxidation reactivity of a Rh(111) model catalyst has been studied in conjunction with the surface structure. The measurements show that it specific thin surface oxide is always present in the high activity regime of Rh-based CO oxidation.

引用

页码：4580 / 4583

页数：4

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