Mathematical modeling of solid-liquid phase-transfer catalysis

被引：40

作者：

Naik, SD ^{[1
]}

Doraiswamy, LK ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem Engn, Ames, IA 50011 USA

来源：

CHEMICAL ENGINEERING SCIENCE | 1997年 / 52卷 / 24期

关键词：

phase-transfer catalysis; solid-liquid systems; mathematical modeling;

D O I：

10.1016/S0009-2509(97)00297-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Use of phase-transfer catalysis (PTC) has been quite common in organic synthesis in the last two decades. However, there are very few publications on the modeling of PTC systems, particularly solid-liquid systems. The present research suggests a systematic procedure for modeling these reactions, which includes reaction both in the liquid and solid phases. The equations describing these models provide a rational basis for the scale-up of PTC reactions. (C) 1997 Elsevier Science Ltd.

引用

页码：4533 / 4546

页数：14

共 29 条

[1] ALKALINE-HYDROLYSIS OF NORMAL-BUTYL ACETATE WITH PHASE-TRANSFER CATALYST ALIQUOT 336 [J].