Intramolecular transport of small-molecule cargo in a nanoscale device operated by light

被引:56
作者
Chen, Jiawen [1 ]
Wezenberg, Sander J. [1 ]
Feringa, Ben L. [1 ]
机构
[1] Univ Groningen, Stratingh Inst Chem, Nijenborgh 4, NL-9747 AG Groningen, Netherlands
基金
欧洲研究理事会;
关键词
INTEGRATED MOTION; MACHINES; CONTRACTION; MOTORS;
D O I
10.1039/c6cc02382g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An intramolecular cargo transport device, based on a light-driven molecular motor, is presented. Detailed UV-vis and H-1 NMR studies demonstrate that the gripper attached to the upper half of the molecular motor is able to pick up an acetyl group from one side of the lower stator and, after a photochemical Z-E isomerization, drop it on the opposite side.
引用
收藏
页码:6765 / 6768
页数:4
相关论文
共 40 条
[1]   A molecular elevator [J].
Badjic, JD ;
Balzani, V ;
Credi, A ;
Silvi, S ;
Stoddart, JF .
SCIENCE, 2004, 303 (5665) :1845-1849
[2]   Artificial molecular-level machines: Which energy to make them work? [J].
Ballardini, R ;
Balzani, V ;
Credi, A ;
Gandolfi, MT ;
Venturi, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :445-455
[3]   Molecular machines [J].
Balzani, V ;
Gómez-López, M ;
Stoddart, JF .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) :405-414
[4]  
Balzani V., 2003, Molecular Devices and Machines, a Journey into the Nanoworld
[5]   Light powered molecular machines [J].
Balzani, Vincenzo ;
Credi, Alberto ;
Venturi, Margherita .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (06) :1542-1550
[6]  
Boy P. D., 1999, NATURE, V402, P247
[7]  
Boyer PD, 1998, ANGEW CHEM INT EDIT, V37, P2297, DOI 10.1002/(SICI)1521-3773(19980918)37:17<2296::AID-ANIE2296>3.0.CO
[8]  
2-W
[9]   Making molecular machines work [J].
Browne, Wesley R. ;
Feringa, Ben L. .
NATURE NANOTECHNOLOGY, 2006, 1 (01) :25-35
[10]   Rotaxane-Based Molecular Muscles [J].
Bruns, Carson J. ;
Stoddart, J. Fraser .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (07) :2186-2199