Triorganotin(IV) complexes of Schiff base derived from 6-amino-2-mercaptobenzothiazole: Synthesis, characterization and X-ray crystal structures

被引：9

作者：

Ma, Chunlin ^{[1
]}

Han, Yawen

Zhang, Rufen

机构：

[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China

[2] Taishan Univ, Dept Chem, Tai An 271021, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 07期

基金：

中国国家自然科学基金;

关键词：

triorganotin(IV); Schiffbase; 6-amino-2-mercaptobenzothiazole; crystal structure;

D O I：

10.1016/j.ica.2006.12.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nine triorganotin(IV) complexes of the type R3SnL (L = L1 R = Me 1, Ph 2, PhCH2 3; L = L2 R = Me 4, Ph 5, PhCH2 6; L = L2 R = Me 7, Ph 8, PhCH2 9) have been obtained by reaction of new Schiff base HL1, HL2 or HL3 with triorganotin(IV) chloride in the presence of sodium ethoxide. All the complexes 1-9 were characterized by elemental, IR and NMR spectra analyses. Except for complexes 3, 4, 6, 9, the others were also characterized by X-ray crystallography diffraction analyses, which revealed that complexes 1, 2, 5, 7, 8 were four coordinated and displayed a capped tetrahedron. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2439 / 2446

页数：8

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