High resolution electronic absorption and extinction coefficients of the allyl radical

被引：3
|
作者：
Bayrakçeken, F [1 ]
Aktas, S
Ünlügedik, A
Karaaslan, I
机构：
[1] Yeditepe Univ, Dept Elect Engn, TR-81120 Istanbul, Turkey
[2] Univ Istanbul, Sch Med, Istanbul, Turkey
[3] Yeditepe Univ, Dept Phys, TR-81120 Istanbul, Turkey
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2003年 / 59卷 / 07期
关键词：
allyl radical; flash spectroscopy; UV-absorption; extinction coefficients; bimolecular decay;
D O I：
10.1016/S1386-1425(02)00393-1
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Electronic absorption spectra in the 210-250 nm region, were reported for the allyl radical in the vapor phase and subsequent reactions have been investigated by kinetic spectroscopy and gas-liquid chromatography. Extinction coefficients are calculated for the strong absorption bands of the allyl free radical by measured rate constants at room temperature. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：1663 / 1666
页数：4
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