Photoinduced NaI-Promoted Radical Borylation of Alkyl Halides and Pseudohalides

被引：14
作者：
Wang, Chenglan [1 ]
Zhou, Lu [2 ]
Yang, Kai [2 ]
Zhang, Feng [2 ]
Song, Qiuling [1 ,2 ,3 ]
机构：
[1] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310000, Zhejiang, Peoples R China
[2] Fuzhou Univ, Coll Chem, Fujian Prov Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
[3] Huaqiao Univ, Inst Next Generat Matter Transformat, Coll Mat Sci Engn, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2021年 / 39卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Borates; Radical reactions; Photochemistry; Metal‐ catalyst free; Aliphatic halide; CATALYZED BORYLATION; ALKYLBORONIC ESTERS; COUPLING REACTIONS; SECONDARY; BROMIDES; TRANSFORMATIONS; REAGENTS;
D O I：
10.1002/cjoc.202100115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Main observation and conclusion A method for photoinduced NaI-promoted radical borylation of aliphatic halides and pseudohalides with bis(catecholato)diboron (B(2)cat(2)) as the boron source is introduced. The borylation reaction is operationally simple and shows high functional group tolerance and broad substrate scope. Preliminary mechanistic studies suggest that the reaction proceeds through S(N)2-based radical-generation strategy.
引用
收藏
页码：1825 / 1830
页数：6
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