Superhydrophobic Coating Derived from the Spontaneous Orientation of Janus Particles

被引：36

作者：

Yang, Tiantian ^{[1
]}

Li, Yuanyuan ^{[1
]}

Gui, Haoguan ^{[2
]}

Du, Deming ^{[2
]}

Du, Yi ^{[2
]}

Song, Xi-Ming ^{[1
]}

Liang, Fuxin ^{[2
]}

机构：

[1] Liaoning Univ, Liaoning Prov Key Lab Green Synth & Preparat Chem, Shenyang 110036, Peoples R China

[2] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 21期

基金：

中国国家自然科学基金;

关键词：

superhydrophobic coating; Janus particle; self-cleaning; chemical durability; mechanical durability; COMPOSITE; SURFACES; NANOPARTICLES; TRANSPARENT; DESIGN;

D O I：

10.1021/acsami.1c05571

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A superhydrophobic surface was achieved using a monolayer of the perpendicularly oriented epoxy-silica@poly-divinylbenzene (PDVB) Janus particles (JPs) on an epoxy resin substrate. The epoxy-silica@PDVB JPs were synthesized from the silica@PDVB/polystyrene (PS) JPs through selective etching of the PDVB/PS belly and the surface modification of the silica part. The modified silica parts can be covalently bonded with the epoxy resin to make the perpendicular orientation spontaneous as well as the coating more robust. The outward PDVB bellies can constitute the micro-/nanoscale hierarchical structures for the superhydrophobic property. The superhydrophobic coating exhibits water repellence and self-cleaning properties. Moreover, the coating exhibits good chemical durability that it can keep the superhydrophobic property after long-time immersion in various aqueous solutions and organic solvents. The coating is still superhydrophobic after water flushing and mechanical wearing, showing the perfect mechanical durability.

引用

页码：25392 / 25399

页数：8

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