Specifics of pyrohydrolytic and solid-phase syntheses of solid solutions in the (MgGa2O4) x (MgFe2O4)1-x system

被引：84

作者：

Ketsko, V. A. ^{[1
]}

Beresnev, E. N. ^{[1
]}

Kop'eva, M. A. ^{[1
]}

Elesina, L. V. ^{[1
]}

Baranchikov, A. I. ^{[1
]}

Stognii, A. I. ^{[2
]}

Trukhanov, A. V. ^{[2
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Natl Acad Sci Belarus, Sci Pract Mat Res Ctr, Minsk 220072, BELARUS

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 03期

关键词：

Citric Acid; Unit Cell Parameter; Metal Nitrate; Solid Phase Synthesis; Oxygen Balance;

D O I：

10.1134/S0036023610030216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work demonstrates the possibility of preparing solid solutions in the (MgGa2O4) (x) (MgFe2O4)(1 - x) system by pyrohydrolytic and solid-phase methods. It is shown that the products obtained have different specific surface areas depending on the ratio between metal nitrates and citric acid. The composition dependence of the unit cell parameter deviates considerably from the Vegard's rule. The compounds obtained are found to be stable up to 300A degrees C, which makes them candidate materials for electronics.

引用

页码：427 / 429

页数：3

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