The relationship of the processing prehistory and thermal stability of a poly(vinyl chloride)-nitrile rubber blend

被引:0
|
作者
Kulish, EI [1 ]
Kolesov, SV [1 ]
Minsker, KS [1 ]
机构
[1] Bashkir State Univ, Ufa 450074, Bashkortostan, Russia
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Influence of the sample preparation conditions on the thermal degradation of PVC was studied using PVC-nitrile rubber blends cast from initial solutions of various concentrations. It was found that various methods of the component blending lead to different kinetic conditions influencing the phase structure of a final blend and, hence, the rate of PVC degradation. It is suggested that a nonequilibrium state of the macromolecular chains in films formed from a polymer blend may lead to accelerated thermal degradation of the blend components.
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页码:127 / 129
页数:3
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