X-ray photoemission studies of BiInO3: Surface termination and effective Debye temperature

被引：8

作者：

Dhingra, Archit ^{[1
]}

Sando, Daniel ^{[2
,3
]}

Lu, Po-Shen ^{[2
]}

Marzouk, Zoe G. ^{[1
]}

Nagarajan, Valanoor ^{[2
]}

Dowben, Peter A. ^{[1
]}

机构：

[1] Univ Nebraska, Dept Phys & Astron, Jorgenson Hall,855 North 16th St, Lincoln, NE 68588 USA

[2] Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia

[3] Univ New South Wales, Mark Wainwright Analyt Ctr, Sydney, NSW 2052, Australia

来源：

JOURNAL OF APPLIED PHYSICS | 2021年 / 130卷 / 02期

基金：

澳大利亚研究理事会; 美国国家科学基金会;

关键词：

PHOTOELECTRON-SPECTROSCOPY; MANGANESE PEROVSKITES; ELECTRONIC-STRUCTURE; OXIDE; XPS; SEGREGATION; POLAR; OXIDATION; CRYSTAL; BISMUTH;

D O I：

10.1063/5.0057556

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

BiInO3 is a potentially polar oxide with distinct optical properties whose origin could result from a surface that has not been well characterized. The surface properties of BiInO3 thin films have been characterized here by temperature dependent angle-resolved x-ray photoemission spectroscopy. A large surface to bulk core-level binding energy shift for the In 3d(5/2) core-level is identified, indicating a surface very different from the bulk. BiInO3 terminates in indium oxide and loses bismuth from the surface of the film at T = 573 K. The Debye-Waller plots suggest effective Debye temperatures of 263 +/- 10 and 556 +/- 27 K for the surface and bulk components of In 3d core-level, respectively.

引用

页数：6

共 43 条

[31] First-principles study of structural, electronic, ferroelectric, and vibrational properties of BiInO3 under high pressure
Kaczkowski, J.
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2019, 134 : 225 - 237
[32] TEMPERATURE-DEPENDENCE OF NORMAL-EMISSION PHOTOELECTRON DIFFRACTION AND ANALOGIES WITH EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE
KEVAN, SD
TOBIN, JG
ROSENBLATT, DH
DAVIS, RF
SHIRLEY, DA
[J]. PHYSICAL REVIEW B, 1981, 23 (02): : 493 - 498
[33] First-principles study of the structure, electronic, and optical properties of orthorhombic BiInO3
Li, Chenliang
Wang, Hai
Wang, Biao
Wang, Rui
[J]. APPLIED PHYSICS LETTERS, 2007, 91 (07)
[34] VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
Momma, Koichi
Izumi, Fujio
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2011, 44 : 1272 - 1276
[35] NEFEDOV VI, 1975, ZH NEORG KHIM+, V20, P2307
[36] Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application
Park, Byung-Wook
Philippe, Bertrand
Zhang, Xiaoliang
Rensmo, Hakan
Boschloo, Gerrit
Johansson, Erik M. J.
[J]. ADVANCED MATERIALS, 2015, 27 (43) : 6806 - +
[37] STUDY OF MIXED-OXIDE CATALYSTS CONTAINING BISMUTH, VANADIUM AND ANTIMONY - PREPARATION, PHASE-COMPOSITION, SPECTROSCOPIC CHARACTERIZATION AND CATALYTIC-OXIDATION OF PROPENE
SCHUHL, Y
BAUSSART, H
DELOBEL, R
LEBRAS, M
LEROY, JM
GENGEMBRE, L
GRIMBLOT, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 : 2055 - &
[38] A Decade with Bismuth-Based Electrodes in Electroanalysis
Svancara, Ivan
Prior, Chad
Hocevar, Samo B.
Wang, Joseph
[J]. ELECTROANALYSIS, 2010, 22 (13) : 1405 - 1420
[39] Perspectives of spin-textured ferroelectrics
Tao, L. L.
Tsymbal, Evgeny Y.
[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2021, 54 (11)
[40] Persistent spin texture enforced by symmetry
Tao, L. L.
Tsymbal, Evgeny Y.
[J]. NATURE COMMUNICATIONS, 2018, 9

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