A molecule-based nanoporous material showing tuneable spin-crossover behavior near room temperature

被引：85
作者：
Quesada, Manuel
de la Pena-O'Shea, Victor A.
Aromi, Guillem
Geremia, Silvano
Massera, Chiara
Roubeau, Olivier
Gamez, Patrick
Reedijk, Jan
机构：
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[3] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy
[4] Univ Parma, Dipartimento Chim Gen & Inorgan Chim Analit Chim, I-43100 Parma, Italy
[5] Univ Bordeaux 1, Ctr Rech Paul Pascal, CNRS, UPR 8641, F-33600 Pessac, France
来源：
ADVANCED MATERIALS | 2007年 / 19卷 / 10期
关键词：
D O I：
10.1002/adma.200602284
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Fe-II-based 1D open framework that exhibits room-temperature spin-crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host-guest properties directly influence the SCO properties.
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页码：1397 / +
页数：7
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