Palladium-Catalyzed Mizoroki-Heck-Type Alkenylation of Monoaryldialkylsulfoniums

被引：33

作者：

Uno, Daisuke ^{[1
]}

Minami, Hiroko ^{[1
]}

Otsuka, Shinya ^{[1
]}

Nogi, Keisuke ^{[1
]}

Yorimitsu, Hideki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2018年 / 13卷 / 17期

关键词：

alkenes; alkenylation; aryl methyl sulfide; arylsulfonium; palladium; BOND-FORMING REACTIONS; C-C; ARYLSULFONIUM SALTS; SULFONIUM SALTS; ARYL; ACTIVATION; HALIDES;

D O I：

10.1002/asia.201800489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mizoroki-Heck-type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts. Various combinations of monoarylsulfoniums and alkenes were adapted to the present reaction. Because monoaryldimethylsulfoniums were readily prepared from the corresponding aryl methyl sulfides and methyl triflate, one-pot alkenylation of aryl methyl sulfide could also be executed.

引用

页码：2397 / 2400

页数：4

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