Novel electrochromic materials based on chalcogenoviologens for smart windows, E-price tag and flexible display with improved reversibility and stability

被引:89
|
作者
Song, Ruitong [1 ]
Li, Guoping [1 ]
Zhang, Yueyan [1 ]
Rao, Bin [1 ]
Xiong, Shanxin [3 ]
He, Gang [1 ,2 ]
机构
[1] Xi An Jiao Tong Univ, Xian Key Lab Sustainable Energy Mat Chem, Frontier Inst Sci & Technol, State Key Lab Strength & Vibrat Mech Struct, Xian 710054, Shaanxi, Peoples R China
[2] South China Univ Technol, Guangdong Prov Key Lab Funct & Intelligent Hybrid, Guangzhou 510640, Peoples R China
[3] Xian Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710054, Shaanxi, Peoples R China
关键词
Electrochromic devices; Viologen; Ionic liquid; Smart windows; E-price tag; THERMOTROPIC LIQUID-CRYSTALLINE; VIOLOGEN; DEVICE; FERROCENE; POLYMERS; OXIDE;
D O I
10.1016/j.cej.2021.130057
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A series of electrochromic composites consisting of chalcogenoviologen-based ionic liquids ([C6EVC6][TFSI]2, E = S, Se, Te) and ferrocene-based ionic liquids ([FcC11ImC1][TFSI]) is reported. Electrochromic devices (ECDs) filled with these composites were assembled, demonstrating multiple colors under different voltages, fast switching times, high color contrast ratio, good reversibility and cycle stability. ECDs working as smart windows on a module house could slow down the room temperature rising in hot weather through changing color. In addition, the eye-catching E-price tag and flexible display devices which can show information dynamically, were assembled successfully. This contribution provided a new kind of electrochromic composites-based smart device for intelligent life.
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页数:8
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