Dome-distortion and fluorine-lined channels: synthesis, and molecular and crystal structure of a metal- and C-H bonds-free fluorophthalocyanine

被引：29

作者：

Lee, HJ

Brennessel, WW

Lessing, JA

Brucker, WW

Young, VG

Gorun, SM ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b303035k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for similar to39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.

引用

页码：1576 / 1577

页数：2

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