Review: Properties chemical reactivity of metallo phthalocyanine and tetramethylbenzoannulene complexes grafted into a polymer

被引：5

作者：

Ferraudi, G. ^{[1
]}

Lappin, A. G. ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 23-24期

关键词：

Coordination complexes; Polymers; Morphology; Thermal reactions; Photochemistry; ELECTRON-TRANSFER REACTIONS; RAY CRYSTAL-STRUCTURES; PULSE-RADIOLYSIS; CYCLAM DERIVATIVES; BLOCK-COPOLYMERS; COPPER-COMPLEXES; REDOX REACTIONS; ZN-II; MACROCYCLES; LIGAND;

D O I：

10.1080/00958972.2014.975221

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The properties of coordination complexes grafted to a polymer backbone are reviewed in this article. The focus is on complexes of phthalocyanine and tetraazaannulene (5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine, also abbreviated tmdbztaa) with various transition metal ions and Al(III). In addition to the morphological characteristics of the materials, their thermal and photochemical reactions are reviewed. Processes such as catalysis of the lignin degrading process and the reduction of CO2 are presented as examples of these materials potential applications.

引用

页码：3822 / 3839

页数：18

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