Hot corrosion behavior and wettability of calcium-magnesium-alumina-silicate (CMAS) on LaTi2Al9O19 ceramic

被引:57
作者
Qu, Weiwei [1 ]
Li, Shusuo [1 ]
Chen, Zehao [1 ]
Li, Chun [1 ]
Pei, Yanling [1 ]
Gong, Shengkai [1 ]
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
基金
中国国家自然科学基金;
关键词
LaTi2Al9O19; ceramic; Thermodynamic calculation; Wettability; Calcium-magnesium-alumina-silicate (CMAS); Anorthite; THERMAL BARRIER COATINGS; Y2O3-STABILIZED ZRO2; RESISTANT; MECHANISMS; AL2O3;
D O I
10.1016/j.corsci.2019.108199
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The development of thermal barrier coating (TBC) has been limited by the calcium-magnesium-alumina-silicate (CMAS) corrosion. In this work, a promising CMAS-resisted LaTi2Al9O19 (LTA) rich in Ti and Al is proposed. CMAS corrosion behavior of LTA ceramics is investigated at a temperature range of 1200 degrees C- 1300 degrees C. By combining the experimental results and thermodynamics analysis, Ca and Si are arrested effectively by formation of CaAl2Si2O8 layer and (Ca,La-0.7)(Ti,Al)O-3 to prevent CMAS from moving downward. Meanwhile, the contact angle of CMAS on LTA is larger than that of YSZ, contributing to the CMAS resistance.
引用
收藏
页数:11
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共 43 条
[1]   Novel thermal barrier coatings that are resistant to high-temperature attack by glassy deposits [J].
Aygun, Aysegul ;
Vasiliev, Alexander L. ;
Padture, Nitin P. ;
Ma, Xinqing .
ACTA MATERIALIA, 2007, 55 (20) :6734-6745
[2]   Wetting of rough surfaces [J].
Chow, TS .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (27) :L445-L451
[3]  
Dean JA., 2004, Lange's Handbook of Chemistry, V70 edn
[4]   Propagation of capillary waves and ejection of small droplets in rapid droplet spreading [J].
Ding, H. ;
Li, E. Q. ;
Zhang, F. H. ;
Sui, Y. ;
Spelt, P. D. M. ;
Thoroddsen, S. T. .
JOURNAL OF FLUID MECHANICS, 2012, 697 :92-114
[5]  
Drexler J. M., 2011, ADV MATER, V23, P2388
[6]   In situ Raman spectroscopy studies of high-temperature degradation of thermal barrier coatings by molten silicate deposits [J].
Garces, Hector F. ;
Senturk, Bilge S. ;
Padture, Nitin P. .
SCRIPTA MATERIALIA, 2014, 76 :29-32
[7]   Microstructural characterization of GZ/CYSZ thermal barrier coatings after thermal shock and CMAS plus hot corrosion test [J].
Gok, Mustafa Guven ;
Goller, Gultekin .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2017, 37 (06) :2501-2508
[8]   Calcium-magnesium-alumina-silicate (CMAS) resistance property of BaLn2Ti3O10 (Ln=La, Nd) for thermal barrier coating applications [J].
Guo, Lei ;
Li, Mingzhu ;
Yang, Chenxi ;
Zhang, Chenglong ;
Xu, Luming ;
Ye, Fuxing ;
Dan, Chengyi ;
Ji, Vincent .
CERAMICS INTERNATIONAL, 2017, 43 (13) :10521-10527
[9]  
Hasz W.C., 1999, US patent, Patent No. 5871820
[10]  
Haynes WM., 2016, CRC handbook of chemistry and physics: A ready-reference book of chemical and physical data