Enyne Ring-rearrangement/Cross-metathesis reactions of cyclic enones

被引：0

作者：

Imhof, S ^{[1
]}

Blechert, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

SYNLETT | 2003年 / 05期

关键词：

ring-rearrangement; metathesis; Diels-Alder cycloaddition; enyne; enones;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of efficient ring rearrangement metathesis reactions of cyclic enones involving cross-metathesis is reported. The resulting trienes from these reactions are substrates for intramolecular Diels-Alder cycloaddition reactions. Thus, the synthesis of highly stereoselective fused tricyclic products in four distinct steps is achieved.

引用

页码：609 / 614

页数：6

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