Enyne Ring-rearrangement/Cross-metathesis reactions of cyclic enones

被引：0
|
作者：
Imhof, S [1 ]
Blechert, S [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
SYNLETT | 2003年 / 05期
关键词：
ring-rearrangement; metathesis; Diels-Alder cycloaddition; enyne; enones;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The use of efficient ring rearrangement metathesis reactions of cyclic enones involving cross-metathesis is reported. The resulting trienes from these reactions are substrates for intramolecular Diels-Alder cycloaddition reactions. Thus, the synthesis of highly stereoselective fused tricyclic products in four distinct steps is achieved.
引用
收藏
页码：609 / 614
页数：6
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