Preparation and upconversion luminescence of YVO4:Er3+, Yb3+

被引:0
作者
Zhang, Yong-ming [1 ]
Li, Yan-hong [1 ]
Li, Peng [1 ]
Hong, Guang-yan [2 ]
Yu, Ying-ning [2 ]
机构
[1] Shenyang Inst Chem Technol, Sch Mat Sci & Engn, Shenyang 110142, Peoples R China
[2] Chinese Acad Sci, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
关键词
yttrium vanadate; rare earth doped materials; precipitation method; upconversion luminescence; NANOCRYSTALS; Y2O3-ER3+; CRYSTALS; RED;
D O I
10.1007/s12613-010-0218-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
YVO4:Er3+, Yb3+ with varying Yb3+ concentrations were prepared by a precipitation method. The results of X-ray diffraction (XRD) show that all the samples have a tetragonal zircon structure; the calculated average crystallite sizes are in the range of 14-22 nm. The lattice constants and cell volume of the samples decrease slightly with the increase in Yb3+ concentration. The upconversion luminescence spectra of all the samples were studied under 980 nm laser excitation. The strong green emission is observed, which is attributed to the H-2(11/2)-> I-4(15/2) and S-4(3/2)-> I-4(15/2) transitions of Er3+, and the red emission peaks in 650-675 nm can be ignored. The emission intensity for the sample depends on the Yb3+ concentration. These results reveal that the upconversion processes of YVO4:Er3+, Yb3+ are related to the structure and the doping Yb3+ concentration of the sample.
引用
收藏
页码:225 / 228
页数:4
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