Sulfonated Polyethylene Glycol (PEG-SO3H) as Eco-Friendly and Potent Water Soluble Solid Acid for Facile and Green Synthesis of 1,8-Dioxo-Octahydroxanthene and 1, 8-Dioxo-Decahydroacridine Derivatives

被引：11

作者：

Hasaninejad, Alireza ^{[1
]}

Shekouhy, Mohsen ^{[1
]}

Miar, Marzieh ^{[2
]}

Firoozi, Somayeh ^{[1
]}

机构：

[1] Persian Gulf Univ, Dept Chem, Fac Sci, Bushehr 75169, Iran

[2] Islamic Azad Univ, Gachsaran Branch, Dept Chem, Fac Sci, Gachsaran, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 01期

关键词：

green chemistry; sulfonated polyethylene glycol; 1; 8-dioxo-octahydroxanthene; 8-dioxo-decahydroacridines; heterocyclic compounds; SOLVENT-FREE; EFFICIENT SYNTHESIS; AROMATIC-ALDEHYDES; IONIC LIQUID; 3-COMPONENT SYNTHESIS; 4-COMPONENT SYNTHESIS; PROMOTED SYNTHESIS; SULFURIC-ACID; CATALYST-FREE; CONDENSATION;

D O I：

10.1080/15533174.2014.900799

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work, a green, simple, and highly efficient procedure for the preparation of 1,8-dioxo-octahydroxanthene and 1,8-dioxo-decahydroacridine derivatives (as biologically active heterocycles, fluorescence materials and Pharmaceutical compounds) is described. Sulfonated polyethylene glycol (PEG-SO3H) has been used as an efficient and reusable catalyst for the one-pot multi component domino condensation reaction of dimedone and an aromatic aldehyde without/and a primary amine. The reactions were completed at 80 degrees C in water as green solvent. Using this procedure, all the products were obtained in good to excellent yields. The catalyst has been recovered and reused several times without any lose of reactivity.

引用

页码：151 / 157

页数：7

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