An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks

被引：9

作者：

Guo, Zhiyong ^{[1
]}

Su, Shengqun ^{[1
]}

Deng, Ruiping ^{[1
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 51卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Biphenyl-3; 4'; 5-tricarboxylate; (H3BPT); Crystal structure; Free carboxylic acids; Antiferromagnetic interaction; MAGNETIC-PROPERTIES; PENTANUCLEAR; RELAXATION; NETWORK; BINDING; LIGAND; UNITS;

D O I：

10.1016/j.inoche.2014.10.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D metal-organic framework (MOF), [Co-3(mu(3)-OH)(mu(2)-H2O)(BPT)(HBPT)(DMF)(2)] (DMF)(H2O) (1) (DMF = N, N'-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4', 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：9 / 12

页数：4

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