[bmIm]OH-catalyzed amidation of azides and aldehydes: an efficient route to amides

被引：15
|
作者：
Gu, Lijun [1 ,2 ]
Wang, Wei [1 ]
Liu, Jiyan [1 ]
Li, Ganpeng [1 ]
Yuan, Minglong [2 ]
机构：
[1] Yunnan Minzu Univ, State Ethn Affairs Commiss & Minist Educ, Key Lab Chem Ethn Med Resources, Kunming 650500, Yunnan, Peoples R China
[2] Yunnan Minzu Univ, Engn Res Ctr Biopolymer Funct Mat Yunnan, Kunming 650500, Yunnan, Peoples R China
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 09期
关键词：
IONIC LIQUID; OXIDATIVE AMIDATION; MILD CONDITIONS; COPPER; AMINES; KETONES; 1,2,3-TRIAZOLES; CARBONYLATION; ALKYLATION; CATALYSIS;
D O I：
10.1039/c6gc00402d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A [bmIm]OH-catalyzed amidation of azides and aldehydes is reported. This reaction is easily handled and proceeds under mild conditions. The overall transformation involves azide-enolate cycloaddition, which subsequently undergoes rearrangement to give amides. Importantly, the employment of ionic liquid makes this transformation green and practical.
引用
收藏
页码：2604 / 2608
页数：5
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