Synthesis and spectroscopic investigation of some iron(III) complexes

被引：0
|
作者：
Singh, B [1 ]
Sahai, P [1 ]
机构：
[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1998年 / 28卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chelating behaviour of neutral and deprotonated (anionic) 2-acetylthiophene-2-furoylhydrazone (Hatfh), 2-acetylfuran-2-furoylhydrazone (Haffh), 2-acetylpyridine-2-furoylhydrazone (Hapfh) and Omega-hydroxyacetophenone-2-furoylhydrazone (H(2)hafh) has been investigated in the complexs of iron(III). The hydrazones react with ferric chloride to yield complexes of the types [Fe(HL)Cl-2(OH)] [HL = Hatfh, Hapfh], Fe(Hatfh)(2)Cl-2(OH) Fe(Hhafh)Cl-2(H2O), Fe-2(L-3)(OH)(3)(H2O) HL = Hatfh, Haffh, Hapfh] and Fe(Hhafh)(3). The complexes have been characterized by elemental analysis, molar conductance, magnetic susceptibility, electronic, infrared and Mossbauer spectral studies and their stereochemistries are discussed.
引用
收藏
页码：587 / 601
页数：15
相关论文
共 50 条
  • [31] ELECTROCHEMICAL, SPECTROELECTROCHEMICAL AND X-RAY-ABSORPTION SPECTROSCOPIC STUDY OF SOME IRON(II) AND IRON(III) POLYPYRAZOLYLBORATO COMPLEXES
    ZAMPONI, S
    GAMBINI, G
    CONTI, P
    LOBBIA, GG
    MARASSI, R
    BERRETTONI, M
    CECCHI, P
    POLYHEDRON, 1995, 14 (13-14) : 1929 - 1935
  • [32] Investigating the interaction between novel polynuclear iron(III) and copper(II) complexes and carbohydrates: Synthesis, structure, and spectroscopic investigation of their interactions with monosaccharides
    Stewart, Christopher D.
    Bawazir, Huda
    Arman, Hadi
    Musie, Ghezai T.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [33] Synthesis, Characterization, and Spectroscopic Investigation of New Iron(III) and Copper(II) Complexes of a Carboxylate Rich Ligand and Their Interaction with Carbohydrates in Aqueous Solution
    Stewart, Christopher D.
    Arman, Hadi
    Bawazir, Huda
    Musie, Ghezai T.
    INORGANIC CHEMISTRY, 2014, 53 (20) : 10974 - 10988
  • [34] SYNTHESIS OF SOME COMPLEXES OF CHROMIUM(III)
    BANERJEA, D
    ROY, J
    SARKAR, S
    INDIAN JOURNAL OF CHEMISTRY, 1970, 8 (04): : 372 - &
  • [35] SYNTHESIS AND SPECTROSCOPIC INVESTIGATION ON DIORGANOTIN(IV) COMPLEXES WITH SOME ARYLAZO-2-PYRIDINE
    BAUL, TSB
    DEY, D
    MISHRA, DD
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1993, 23 (01): : 53 - 65
  • [36] MOSSBAUER SPECTROSCOPIC STUDY OF THE REDUCTIVE DECOMPOSITION OF IRON(III) COMPLEXES
    ZAY, I
    VERTES, A
    NAGY, GT
    SUBA, M
    BURGER, K
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1985, 88 (02) : 343 - 350
  • [37] MOSSBAUER SPECTROSCOPIC INVESTIGATION OF SOME EUROPIUM(III) DIKETONATES
    LYLE, SJ
    WITTS, AD
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (03): : 185 - 188
  • [38] Synthesis, characterization and in vitro antiprotozoal studies of iron(III) complexes of some antimalarial drugs
    Ajibade, Peter A.
    Kolawole, Gabriel A.
    JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (21) : 3367 - 3374
  • [39] REDOX REACTIONS OF SOME IRON(II), IRON(III), AND COBALT(III) PICOLINATE COMPLEXES
    LANNON, AM
    LAPPIN, AG
    SEGAL, MG
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03): : 619 - 624
  • [40] SPECTROSCOPIC INVESTIGATION OF SOME RARE EARTH IRON GARNETS
    HUFNER, S
    SCHMIDT, H
    PHYSIK DER KONDENSITERTEN MATERIE, 1965, 4 (04): : 262 - +
12345