Kinetic investigation of a chemical process in single-molecule junction

被引：13
|
作者：
Hasegawa, Yusuke [1 ]
Harashima, Takanori [1 ]
Jono, Yuki [1 ]
Seki, Takumi [1 ]
Kiguchi, Manabu [1 ]
Nishino, Tomoaki [1 ]
机构：
[1] Sch Sci, Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 02期
关键词：
ANCHORING GROUPS; CONDUCTANCE; STABILITY; ELECTRONICS; CONTACT; CHEMISTRY; FORCE;
D O I：
10.1039/c9cc08383a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we report on the kinetic investigation for the breakdown of single-molecule junctions. Current through the junctions was measured as a function of time to elucidate their lifetimes. The analysis of the lifetimes revealed that the breakdown reaction obeys first-order reaction kinetics, and the rate constants determined from the analysis were found to reflect the stability of the junctions.
引用
收藏
页码：309 / 312
页数：4
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