Robust Aqueous Zn-Ion Fiber Battery Based on High-Strength Cellulose Yarns

被引:43
作者
Yi, Huihua [1 ]
Ma, Yue [1 ]
Zhang, Shuang [1 ]
Na, Bing [1 ]
Zeng, Rong [1 ]
Zhang, Yu [1 ]
Lin, Chong [1 ]
机构
[1] East China Univ Technol, Sch Chem Biol & Mat Sci, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, 418 Guanglan Rd, Nanchang 330013, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
aqueous Zn-ion battery; cellulose yarn; polyaniline; flexible; sustainable; HIGH-ENERGY DENSITY; CATHODE; SUPERCAPACITOR; NANOTUBES; SPUN; LI;
D O I
10.1021/acssuschemeng.9b04188
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fiber batteries are easily integrated with textiles to power wearable electronics because of their one-dimensional shape. Fiber batteries should meet the requirements of excellent mechanical strength, flexibility, durability, and superior electrochemical performance. Herein, high-strength cellulose yarns, lightweight, low-cost, and sustainable, are adopted as robust and flexible substrates of both cathode (polyaniline) and anode (metal Zn) of an aqueous Zn-ion fiber battery. The fiber battery delivers an energy density of 153.2 and 61.1 Wh/kg at a power density of 0.16 and 6.5 kW/kg, respectively (based on the total active mass of the cathode and anode). Meanwhile, superior cyclic stability and high flexibility are exhibited by the fiber battery. The capacity retention is 91.9% and 97.5% after 1000 charge/discharge and bending cycles, respectively. Impressively, the fiber battery works well under a mechanical load of 100 g to power an LED indicator.
引用
收藏
页码:18894 / 18900
页数:13
相关论文
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ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (04) :5314-5321