Oxidative coupling of cycloalkanones with 3-(pyridin-2-yl)-1,2,4-triazinone coordinated to Pd(II)

被引：1

作者：

El-Abadelah, Mustafa M. ^{[1
]}

Awwadi, Firas F. ^{[1
]}

Hodali, Hamdallah A. ^{[1
]}

Rawajfeh, Rasha S. ^{[1
]}

Zreid, Monther S. ^{[1
]}

Voelter, Wolfgang ^{[2
]}

机构：

[1] Univ Jordan, Fac Sci, Chem Dept, Amman 11942, Jordan

[2] Univ Tubingen, Interfak Inst Biochem, Hoppe Seyter Str 4, D-72076 Tubingen, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2018年 / 73卷 / 08期

关键词：

cyclohexanone; cyclopentanone; oxidative C-C coupling; Pd-pyridyl-1,2,4-triazinone; X-ray crystal structures; NICKEL(II);

D O I：

10.1515/znb-2018-0077

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichloro[3-(pyridin-2-yl)-1,2,4-triazinone] Pd(II) undergoes oxidative C-C coupling reaction with cyclopentanone and cyclohexanone at 110 degrees C to yield the respective Pd complexes, chloro[1(4-chlorophenyl)-5-(2-hydroxycyclopent-1-enyl)-3-(pyridin-2-yl)-1,2,4-triazin-6(1H)-one]palladium(II) (3) and chloro[1-(4-chlorophenyl)-5-(2-hydroxycyclohex-1-enyl)-3(pyridin-2-yl)-1,2,4-triazin-6(1H)-one]palladium(II) (4). The structures of both complexes are supported by spectral data and confirmed by single-crystal X-ray crystallography. The molecules 3 and 4 stack to form tunnel structures, whilst the geometry around the palladium ion is square planar.

引用

页码：583 / 587

页数：5

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