1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals

被引：14
作者：
Riccobono, Alessio [1 ,2 ]
Parker, Rachel R. [2 ]
Whitwood, Adrian C. [2 ]
Slattery, John M. [2 ]
Bruce, Duncan W. [2 ]
Pibiri, Ivana [1 ]
Pace, Andrea [1 ]
机构：
[1] Univ Palermo, Dipartimento Sci & Tecnol, Biol Chim & Farmaceut STEBICEF, Via Sci Edificio 17, I-90128 Palermo, Italy
[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 71期
关键词：
FLUORINATED HETEROCYCLIC-COMPOUNDS; IMIDAZOLIUM SALTS; CATIONS; 1,2,4-OXADIAZOLES; ELECTROLYTES; CONDUCTIVITY; DESIGN; ANIONS; SERIES;
D O I：
10.1039/c8cc04704a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel scaffold for the construction of self-organised ionic liquids and ionic liquid crystals bearing both perfluorocarbon and hydrocarbon moieties has been developed. The phase behaviour and physical properties of these materials can be tuned as a function of chain length and fluorine content and significant structural elaboration is possible, giving a highly flexible system.
引用
收藏
页码：9965 / 9968
页数：4
相关论文
共 44 条
[1]   Anisotropic ionic conductivity in fluorinated ionic liquid crystals suitable for optoelectronic applications [J].
Abate, Antonio ;
Petrozza, Annamaria ;
Cavallo, Gabriella ;
Lanzani, Guglielmo ;
Matteucci, Francesco ;
Bruce, Duncan W. ;
Houbenov, Nikolay ;
Metrangolo, Pierangelo ;
Resnati, Giuseppe .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (22) :6572-6578
[2]   Triazolium cations: from the "click" pool to multipurpose applications [J].
Aizpurua, Jesus M. ;
Fratila, Raluca M. ;
Monasterio, Zaira ;
Perez-Esnaola, Nerea ;
Andreieff, Elena ;
Irastorza, Aitziber ;
Sagartzazu-Aizpurua, Maialen .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (02) :474-480
[3]   Effect of Fluorination and Size of the Alkyl Side-Chain on the Solubility of Carbon Dioxide in 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide Ionic Liquids [J].
Almantariotis, D. ;
Gefflaut, T. ;
Padua, A. A. H. ;
Coxam, J. -Y. ;
Gomes, M. F. Costa .
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (10) :3608-3617
[4]   Thermotropic Ionic Liquid Crystals [J].
Axenov, Kirill V. ;
Laschat, Sabine .
MATERIALS, 2011, 4 (01) :206-259
[5]   The Bright Future of Unconventional σ/-Hole Interactions [J].
Bauza, Antonio ;
Mooibroek, Tiddo J. ;
Frontera, Antonio .
CHEMPHYSCHEM, 2015, 16 (12) :2496-2517
[6]   Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: origins, current status and discussion [J].
Brammer, Lee .
FARADAY DISCUSSIONS, 2017, 203 :485-507
[7]   Liquid-Crystalline Ionic Liquids as Ordered Reaction Media for the Diels-Alder Reaction [J].
Bruce, Duncan W. ;
Gao, Yanan ;
Canongia Lopes, Jose Nuno ;
Shimizu, Karina ;
Slattery, John M. .
CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (45) :16113-16123
[8]   Fluorinated heterocyclic compounds.: An effective strategy for the synthesis of fluorinated Z-oximes of 3-perfluoroalkyl-6-phenyl-2H-1,2,4-triazin5-ones via a ring-enlargement reaction of 3-benzoyl-5-perfluoroalkyl-1,2,4-oxadiazoles and hydrazine [J].
Buscemi, S ;
Pace, A ;
Piccionello, AP ;
Macaluso, G ;
Vivona, N ;
Spinelli, D ;
Giorgi, G .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (08) :3288-3291
[9]   Fluorinated heterocyclic compounds - The first example of an irreversible ring-degenerate rearrangement on five-membered heterocycles by attack of an external bidentate nucleophile [J].
Buscemi, S ;
Pace, A ;
Pibiri, I ;
Vivona, N ;
Lanza, CZ ;
Spinelli, D .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (05) :974-980
[10]   Fluorinated heterocyclic compounds. An expedient route to 5-perfluoroalkyl-1,2,4-triazoles via an unusual hydrazinolysis of 5-perfluoroalkyl-1,2,4-oxadiazoles: First examples of an ANRORC-like reaction in 1,2,4-oxadiazole derivatives [J].
Buscemi, S ;
Pace, A ;
Pibiri, I ;
Vivona, N ;
Spinelli, D .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02) :605-608
12345