A Biomass-Based Integral Approach Enables Li-S Full Pouch Cells with Exceptional Power Density and Energy Density

被引:29
作者
Liu, Yuping [1 ,2 ]
Barnscheidt, Yvo [3 ]
Peng, Manhua [1 ,2 ]
Bettels, Frederik [1 ,2 ]
Li, Taoran [1 ,2 ]
He, Tao [1 ,2 ]
Ding, Fei [1 ,2 ]
Zhang, Lin [1 ,2 ]
机构
[1] Leibniz Univ Hannover, Inst Solid State Phys, Appelstr 2, D-30167 Hannover, Germany
[2] Leibniz Univ Hannover, Lab Nano & Quantum Engn LNQE, Schneiderberg 39, D-30167 Hannover, Germany
[3] Leibniz Univ Hannover, Inst Elect Mat & Devices, Schneiderberg 32, D-30167 Hannover, Germany
关键词
biomass‐ based porous carbon matrices; dendrite‐ free Li anodes; electric vehicles; grid storage; Li‐ S pouch cells; superior energy; power densities; LITHIUM-SULFUR BATTERIES; METAL ANODE; CARBON; PERFORMANCE; COMPOSITE; OPPORTUNITIES; POLYSULFIDES; NANOSHEETS; PHASE;
D O I
10.1002/advs.202101182
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium-sulfur (Li-S) batteries, as part of the post-lithium-ion batteries (post-LIBs), are expected to deliver significantly higher energy densities. Their power densities, however, are today considerably worse than that of the LIBs, limiting the Li-S batteries to very few specific applications that need low power and long working time. With the rapid development of single cell components (cathode, anode, or electrolyte) in the last few years, it is expected that an integrated approach can maximize the power density without compromising the energy density in a Li-S full cell. Here, this goal is achieved by using a novel biomass porous carbon matrix (PCM) in the anode, as well as N-Co9S8 nanoparticles and carbon nanotubes (CNTs) in the cathode. The authors' approach unlocks the potential of the electrodes and enables the Li-S full pouch cells with unprecedented power densities and energy densities (325 Wh kg(-1) and 1412 W kg(-1), respectively). This work addresses the problem of low power densities in the current Li-S technology, thus making the Li-S batteries a strong candidate in more application scenarios.
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页数:8
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