Analysis of the influence on the performance degradation of CdTe solar cells by the front contact

被引:11
作者
Artegiani, Elisa [1 ]
Menossi, Daniele [1 ]
Salavei, Andrei [1 ,2 ]
di Mare, Simone [1 ]
Romeo, Alessandro [1 ]
机构
[1] Univ Verona, Dept Comp Sci, Lab Appl Phys, Ca Vignal 1,Str Le Grazie 15, I-37134 Verona, Italy
[2] Calyxo Gmbh, Bitterfeld, Germany
关键词
Solar cells; Cadmium telluride; Transparent conducting oxide; Stability; FILM;
D O I
10.1016/j.tsf.2016.09.052
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CdTe thin film solar cells have shown to be competitive in terms of scalability and efficiency, the latest record efficiency exceeds 22%. Because of the CdTe high electron affinity the insertion of copper has demonstrated to deliver the highest efficiency device, however degrading the cell. For this reason other possible degradation effects are generally neglected. In this work CdTe solar cells were prepared with different transparent conductive oxides (TCOs), delivering similar conversion efficiencies. However aged cells show that stability is strictly connected with the different TCOs. Analysis of capacitance-voltage and drive level capacitance profiling shows a different defects distribution for solar cells with less stable front contact and admittance spectroscopy highlights the different defects formation after aging. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:101 / 105
页数:5
相关论文
共 13 条
[1]  
Beach J., STUDIES BASIC ELECT
[2]   Deep energy levels in CdTe and CdZnTe [J].
Castaldini, A ;
Cavallini, A ;
Fraboni, B ;
Fernandez, P ;
Piqueras, J .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (04) :2121-2126
[3]   Comparison of electrical and luminescence data for the A center in CdTe [J].
Castaldini, A ;
Cavallini, A ;
Fraboni, B ;
Fernandez, P ;
Piqueras, J .
APPLIED PHYSICS LETTERS, 1996, 69 (23) :3510-3512
[4]   Capacitance profiling in the CIGS solar cells [J].
Cwil, Michal ;
Igalson, Malgorzata ;
Zabierowski, Pawel ;
Kaufmann, Chrystian A. ;
Neisser, Axel .
THIN SOLID FILMS, 2007, 515 (15) :6229-6232
[5]  
DEMTSU S, 2010, IEEE PHOT SPEC CONF, P1161
[6]   SHALLOW DONORS IN CDTE [J].
FRANCOU, JM ;
SAMINADAYAR, K ;
PAUTRAT, JL .
PHYSICAL REVIEW B, 1990, 41 (17) :12035-12046
[7]  
Gilmore A. S., 2002, P 29 IEEE PHOT SPEC, P604
[8]   Bulk and metastable defects in CuIn1-xGaxSe2 thin films using drive-level capacitance profiling [J].
Heath, JT ;
Cohen, JD ;
Shafarman, WN .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (03) :1000-1010
[9]   ACCEPTOR STATES IN CDTE AND COMPARISON WITH ZNTE - GENERAL TRENDS [J].
MOLVA, E ;
PAUTRAT, JL ;
SAMINADAYAR, K ;
MILCHBERG, G ;
MAGNEA, N .
PHYSICAL REVIEW B, 1984, 30 (06) :3344-3354
[10]   Last Progress in CdTe/CdS Thin Film Solar Cell Fabrication Process [J].
Romeo, N. ;
Bosio, A. ;
Menossi, D. ;
Romeo, A. ;
Aramini, Matteo .
2013 ISES SOLAR WORLD CONGRESS, 2014, 57 :65-+