The case for a reactive resonance in F+H2

被引：49
|
作者：
Chao, SD [1 ]
Skodje, RT [1 ]
机构：
[1] Univ Colorado, Dept Chem, Boulder, CO 80309 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2000年 / 113卷 / 09期
关键词：
D O I：
10.1063/1.1289526
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have investigated the F+H-2 reaction on the Stark-Werner potential energy surface using quantum scattering theory, adiabatic theory, and spectral quantization. Clear evidence is found for a transition state resonance on this potential surface. Comparison to experimental results suggests that a resonance is also present in the true reaction. (C) 2000 American Institute of Physics. [S0021-9606(00)01633-0].
引用
收藏
页码：3487 / 3491
页数：5
相关论文
共 50 条
  • [1] Time delay as a tool to identify the signatures of reactive resonance:: F+HD and F+H2 reactions
    Chao, SD
    Skodje, RT
    JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (03): : 1462 - 1472
  • [2] EXPERIMENTAL INVESTIGATION OF RESONANCES IN REACTIVE SCATTERING - THE F+H2 REACTION
    NEUMARK, DM
    WODTKE, AM
    ROBINSON, GN
    HAYDEN, CC
    LEE, YT
    PHYSICAL REVIEW LETTERS, 1984, 53 (03) : 226 - 229
  • [3] The time-delay route to reactive scattering resonances:: the case of the F+H2→HF+H reaction
    Cavalli, Simonetta
    De Fazio, Dario
    PHYSICA SCRIPTA, 2007, 76 (03) : C21 - C27
  • [4] Dynamical resonance in F+H2 chemical reaction and rotational excitation effect
    YANG XueMing 1
    2 Institute of Theoretical and Computational Chemistry
    Chinese Science Bulletin, 2007, (08) : 1009 - 1012
  • [5] Dynamical resonance in F+H2 chemical reaction and rotational excitation effect
    Yang XueMing
    Xie DaiQian
    Zhang DongHui
    CHINESE SCIENCE BULLETIN, 2007, 52 (08): : 1009 - 1012
  • [6] QUANTUM RESONANCE STRUCTURE IN THE 3-DIMENSIONAL F+H2 REACTION
    REDMON, MJ
    WYATT, RE
    CHEMICAL PHYSICS LETTERS, 1979, 63 (02) : 209 - 212
  • [7] ABSOLUTE RATES OF REACTIONS H+ F2 AND F+H2
    WILKINS, RL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1971, (MAR-A): : 76 - &
  • [8] 3-DIMENSIONAL QUANTUM-MECHANICAL STUDY OF F+H2 REACTIVE SCATTERING
    SHAN, Y
    CHOI, BH
    POE, RT
    TANG, KT
    CHEMICAL PHYSICS LETTERS, 1978, 57 (03) : 379 - 384
  • [9] DETAILED DYNAMICS OF COLLINEAR F+H2 TRAJECTORIES
    HUTCHINSON, JS
    WYATT, RE
    JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (07): : 3509 - 3523
  • [10] COMPUTER MODELING OF NONTHERMAL F+H2 REACTIONS
    ROOT, JW
    GRANT, ER
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 173 (MAR20): : 265 - 266
12345